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- Biogenous sediments can allow the reconstruction of past climate history from oxygen isotope ratios. Oxygen atoms exist in three forms, or isotopes, in ocean water: O16, O17 and O18 . O16 is the most common form, followed by O18 . O16 is lighter than O18, so it evaporates more easily, leading to water vapor that has a higher proportion of O16. During periods of cooler climate, water vapor condenses into rain and snow, which forms glacial ice that has a high proportion of O16. The remaining seawater therefore has a relatively higher proportion of O18. Marine organisms which incorporate dissolved oxygen into their shells as calcium carbonate will have shells with a higher proportion of O18 isotope. This means the ratio of O16:O18 in shells is low during periods of colder climate. When climate warms, glacial ice melts releasing O16 from the ice and returning it to the oceans, increasing the O16:O18 ratio in the water. When organisms incorporate oxygen into their shells, the shells will contain a higher O16:O18 ratio. Scientists can therefore examine biogenous sediments, calculate the O16:O18 ratios for samples of known ages, and from those ratios, infer the climate conditions under which those shells were formed. The same types of measurements can also be taken from ice cores; a decrease of 1 ppm O18 between ice samples represents a decrease in temperature of 1.5°C. (en)
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